Ascent Petrochem Holdings Co., Limited
知識について


MSDS of Tall Oil Fatty Acid Amphoteric Imidazoline

1. Identification

Product Name: Tall Oil Fatty Acid Amphoteric Imidazoline
Synonyms: Imidazolinium compound based on tall oil fatty acid
Recommended Use: Corrosion inhibitor, surfactant, emulsifier for industrial applications
Supplier: Manufacturer’s name, including address and contact phone number
Emergency Contact: 24-hour emergency phone for chemical incidents
Relevant Restriction: Not intended for consumer use—industrial and professional applications only
Product Code: Provide unique identifier assigned by manufacturer for traceability

2. Hazard Identification

Hazard Classification: Eye irritation (Category 2A), Skin irritation (Category 2), Aquatic chronic toxicity (Category 3)
Label Elements (GHS): Exclamation mark, hazard statements for skin and eye irritation
Signal Word: Warning
Hazard Statements: Causes skin irritation, causes serious eye irritation, harmful to aquatic life with long lasting effects
Precautionary Statements: Wear protective gloves/eye protection, wash skin thoroughly after handling, avoid release to environment

3. Composition / Information on Ingredients

Chemical Identity: Tall oil fatty acid imidazoline derivative (main constituent approx. 70–90%)
CAS Number: 61791-47-7 (for imidazoline compound), tall oil fatty acids: 61790-12-3
Other Ingredients: Water, trace impurities arising from raw materials and manufacture (less than 10%)
Impurities and Stabilizing Additives: No substances present in concentrations that present significant risk

4. First Aid Measures

General Recommendations: Call physician if serious symptoms develop or the affected individual is in distress
Inhalation: Remove to fresh air, monitor for respiratory symptoms
Skin Contact: Remove contaminated clothing, wash skin with soap and water for several minutes
Eye Contact: Rinse eyes gently with water for 15 minutes, keep eyelids open, seek immediate medical attention
Ingestion: Do not induce vomiting, rinse mouth with water, seek medical help if feeling unwell
Most Important Symptoms: Irritation, redness, possible dermatitis; respiratory discomfort in poorly ventilated spaces
Immediate Medical Attention: Recommended for eye exposure or if symptoms persist in any route

5. Fire-Fighting Measures

Suitable Extinguishing Media: Water fog, dry chemical, foam, carbon dioxide
Unsuitable Extinguishing Media: Direct water jet in high pressure—spreading risk
Hazardous Combustion Products: Carbon oxides, nitrogen oxides, possible amines under fire conditions
Specific Hazards: Oil-based product can smoke and splatter if heated excessively
Special Protective Equipment for Firefighters: Full protective gear, positive pressure self-contained breathing apparatus, chemical-resistant gloves
Firefighting Instructions: Cool tanks with water spray; evacuate area if containers are compromised

6. Accidental Release Measures

Personal Precautions: Use personal protective equipment; avoid direct skin and eye contact
Emergency Procedures: Isolate area, ventilate if in confined space, keep unprotected people away
Spill Containment: Dike and absorb with inert materials (sand, earth, absorbent pads for oil)
Cleaning Up: Collect residue for chemical waste disposal, wash area with plenty of water
Environmental Precautions: Prevent release to drains, surface water, or soil—recover product as much as feasible, report significant releases
Decontamination: Dispose of contaminated cleaning rags and absorbents as chemical waste

7. Handling and Storage

Precautions for Safe Handling: Wear gloves, goggles, and protective clothing; prevent eye and skin contact
Hygiene Measures: Do not eat, drink, smoke, or use personal devices while handling
Incompatible Materials: Strong oxidizing agents, strong acids, some metals at high temperatures
Technical Measures: Ensure appropriate ventilation; use closed systems where possible
Storage Conditions: Store in tightly closed containers, preferably at room temperature or cooler
Storage Location: Keep away from heat, direct sunlight, incompatible substances; designate chemical storage space
Container Materials: Preferred—plastic drums, coated steel; avoid uncoated iron

8. Exposure Controls / Personal Protection

Occupational Exposure Limits: No specific limits for this product; minimize exposure by good practice
Engineering Controls: Local exhaust ventilation in work area
Personal Protective Equipment: Chemical resistance gloves (nitrile or similar), safety goggles or face shield, long-sleeved clothing
Respiratory Protection: If exposure limits concern, use approved organic vapor filter mask
Hygiene Wash Facilities: Eye-wash stations and safety showers near work area
Monitoring: Observe for signs of irritation among staff, regular review of work practices for improvement

9. Physical and Chemical Properties

Appearance: Amber to yellowish liquid, viscous
Odor: Mild fatty, amine-like
pH (1% Solution): Slightly alkaline (approx. 8–9)
Melting/Freezing Point: Below -10°C
Boiling Point/Range: Greater than 200°C (decomposes at high temperature)
Flash Point: Around 150°C (Closed cup method—seek manufacturer’s value)
Evaporation Rate: Negligible at ambient temperature
Solubility: Partial in water (dispersible/emulsifiable), soluble in most organic solvents
Density: 0.95–1.02 g/cm³ at 20°C
Viscosity: Moderate to high, depends on temperature
Partition Coefficient (n-octanol/water): Greater than zero—suggests some accumulation in biota
Auto-Ignition Temperature: Above 300°C

10. Stability and Reactivity

Chemical Stability: Stable at normal temperatures in sealed containers
Possible Hazardous Reactions: None expected under normal conditions, but reacts with strong oxidizers
Conditions to Avoid: High heat, open flame, incompatible materials
Incompatible Materials: Strong acids, oxidizers, some reactive metals
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide, ammonia, nitrogen oxides under fire conditions
Polymerization: No hazardous polymerization expected

11. Toxicological Information

Likely Routes of Exposure: Skin contact, eye contact, ingestion, inhalation of aerosols
Acute Toxicity: Not considered acutely toxic based on available data (LD50 oral >2000 mg/kg in rats)
Skin Corrosion/Irritation: Moderate skin irritant with repeated exposure
Serious Eye Damage/Irritation: Causes eye irritation, risk of corneal injury if splashed
Respiratory or Skin Sensitization: No evidence of respiratory sensitization, rare cases of skin sensitization
Chronic Effects: Prolonged exposure may cause dermatitis or eczema; no firm data showing carcinogenicity or reproductive hazards
Target Organs: Skin, eyes; very high oral doses may impact gastrointestinal tract

12. Ecological Information

Aquatic Toxicity: Harmful to aquatic organisms with potential for long-term effects (LC50 for fish and invertebrates typically in the range of 1–10 mg/L)
Persistence and Degradability: Biodegradable over weeks under aerobic conditions, slow under anaerobic
Bioaccumulation Potential: Moderate based on partition coefficients, risk increases with repeat exposure
Mobility in Soil: Binds to soil particles; modest risk of leaching
Other Effects: Surfactant action can harm aquatic life by affecting gill function or egg membranes
Product Fate: Microbial breakdown is primary removal path after release
Special Precautions: Avoid contamination of water courses and suggest containment for washing areas

13. Disposal Considerations

Waste Disposal Recommendations: Dispose of as hazardous chemical waste according to local and national regulations
Methods: Prefer incineration or chemical treatment by licensed facility; do not pour down drain
Contaminated Packaging: Empty containers fully, rinse if possible; treat as hazardous waste
Special Precautions: Store waste securely—label containers with contents and hazards
Regulatory References: Follow RCRA, local hazardous waste rules; consult waste contractor for onsite requirements

14. Transport Information

UN Number: Not classified as dangerous goods under most international shipping standards; check IMDG for marine transport
Shipping Name: Tall Oil Fatty Acid Derivative, liquid, NOS (if applicable)
Transport Hazard Class: Not routinely assigned, but always check current regulations for any changes
Packing Group: Usually not assigned; use properly sealed and labeled drums or totes
Marine Pollutant: Yes, under most environmental shipping codes—mark accordingly
Special Transport Precautions: Prevent spillage, keep packaging upright, avoid heat, secure during transit
Transport Labels: Standard handling and environmental warnings recommended

15. Regulatory Information

Global Inventory Status: Listed in main chemical inventories (TSCA, EINECS/REACH, DSL, AICS, NZIoC, PICCS, IECSC); check updates for composition variations
SARA Title III: Not regulated as Extremely Hazardous Substance, some release reporting may apply depending on volume
State and Federal Regulations: Product subject to workplace labeling and hazard communication in accordance with OSHA’s Hazard Communication Standard
Labeling Requirements: Complies with GHS and national hazard communication requirements—ensure workplaces update SDS annually
Additional Restrictions: Check for local worker protection, environment control, and water pollution regulations
Workplace Training: Required in most jurisdictions under chemical safety law
Other Recommendations: Monitor developments in chemical safety regulation for possible reclassification of components that could affect safe use